It is customary to write through such a formula - Br2, although it is in solution in the form of a mixture of two acids - HBrO (hypochlorous acid) and HBr. This compound has a yellow-orange color and a rather low freezing point. It is a strong oxidizing agent that is capable of oxidizing cations of such metals in an alkaline environment - Cr +3, Mn +3, Fe +2, Co + 2, Ni +3. The addition of Br 2 reduces the pH of the solution (pH), because bromine water contains free acids.
This is a chemically active substance that can interact with both inorganic and organic substances. Let's consider some chemical processes with this compound.
Discoloration of bromine water serves everything To carry out such an experiment, it is necessary to mix a small amount of any alkene or alkyne in a test tube with Br 2 . In the course of this reaction, bromine atoms are added at the site of the double or triple bond rupture. The disappearance of the yellow-orange color during this interaction is proof of the unsaturation of the hydrocarbon taken.
The chemical reaction "phenol - bromine water" is used to precipitate bromine-substituted compounds from solutions. If this interaction of substances is carried out in an anhydrous environment, then the formation of tribromophenol will take a couple of days. Therefore, a small amount of H 2 O is added as a catalyst.
Bromine water in the laboratory is prepared as follows: 250 ml of distilled water is added to 1 ml of bromine, while vigorously stirring. The prepared solution is stored in a tightly closed dark glass container. If the prepared Br 2 is stored in the light or in a light bottle, oxygen will be released due to the hypobromous acid content. Work on the preparation of the reagent is carried out in a fume hood. Since bromine itself is poisonous, and bromine water contains it, care must be taken when working with it.
It is also necessary to take into account the fact that when Br 2 gets on the skin, severe itching appears, and with prolonged exposure, ulcers can occur. If the substance has got on the skin, it should be washed with plenty of water, and then in case of a large wound surface or deep lesions of the epidermis, the skin is additionally lubricated with an ointment, which includes NaHCO 3 .
Bromine water is widely used in chemical analysis and synthesis of organic preparations. So, it is used in the production of bromine-containing drugs. And here you need to be careful, because. prolonged use of them can lead to a disease - bromism. The main symptoms are apathy, lethargy, the appearance of a skin rash. For faster removal of bromine ions from the body, a diet with a high salt content and plenty of fluids are followed. Bromine water is also used in the intermediate stages of the production of flame retardants - substances that protect against ignition. They impregnate fabrics, wood, building material.
Br 2 at ordinary temperature is a brownish-brown heavy liquid that forms toxic red-brown vapors with a pungent odor. The solubility of bromine in water is higher than that of chlorine. A saturated solution of Br 2 in water is called "bromine water".
Free I 2 at ordinary temperature is a black-gray solid with a violet tint, has a noticeable metallic luster. Iodine sublimes easily, has a peculiar smell (iodine vapor, like bromine, is very poisonous). The solubility of I 2 in water is the smallest among all halogens, but it dissolves well in alcohol and other organic solvents.
How to get
1. Bromine and iodine are extracted from sea water, underground brines and drilling waters, where they are contained in the form of Br - and I - anions. The release of free halogens is carried out using various oxidizing agents, most often gaseous chlorine is passed through:
2NaI + Cl 2 \u003d I 2 + 2NaCl
2NaBr + Cl 2 \u003d Br 2 + 2NaCI
2. Under laboratory conditions, for example, the following reactions are used to obtain Br 2 and I 2:
2NaBr + MnO 2 + 2H 2 SO 4 = Br 2 ↓ + MnSO 4 + Na 2 SO 4 + 2H 2 O
bHBr + 2H 2 SO 4 = 3Br 2 ↓ + S↓ + 4Н 2 O
2HI + H 2 SO 4 \u003d I 2 ↓ + SO 2 + 2H 2 O
Chemical properties
Bromine and iodine are chemically similar to chlorine. The differences are mainly related to the reaction conditions. Let us note some important features of chemical reactions involving Br 2 and I 2 .
Br 2 is a very strong oxidizer
Bromine is a liquid, unlike gaseous Cl 2, so the concentration of molecules in it is higher. This explains the stronger oxidizing effect of liquid bromine. For example, when iron and aluminum come into contact with it, ignition occurs even at ordinary temperatures.
Bromine water - a reagent for conducting qualitative reactions
Bromine water has a yellow-brown color, which quickly disappears if the dissolved Br 2 reacts with any substance. "Bromine water decolorization" is a test for the presence in a solution of a number of inorganic and organic substances.
1. Detection of reducing agents in solutions
Gaseous and dissolved in water SO 2 and H 2 S, as well as soluble sulfites and sulfides decolorize bromine water:
Br 2 + Na 2 SO 3 + H 2 O \u003d 2HBr + Na 2 SO 4
Br 2 + H 2 S \u003d 2HBr + S ↓
3Br 2 + Na 2 S + ZN 2 O \u003d 6HBr + Na 2 SO 3
2. Detection of multiple carbon-carbon bonds
Qualitative reaction to unsaturated organic compounds - discoloration of bromine water:
R-CH=CH-R" + Br 2 → R-CHBr-CHBr-R"
3. Detection of phenol and aniline in organic solutions
Phenol and aniline easily interact with bromine water, and the reaction products do not dissolve in organic solvents, therefore they form precipitates:
C 6 H 5 OH + ZBr 2 → C 6 H 2 Br 3 OH ↓ + ZHBr 2
С 6 Н 5 NH 2 + ЗВr 2 → С 6 H 2 Br 3 NH 2 ↓ + ЗНВr
Iodine-starch reaction in a qualitative analysis
Anions I - are very easily oxidized by both strong and weak oxidizing agents:
2I - -2e - → I 2
Even small amounts of I 2 released can be detected using a starch solution, which acquires a characteristic dirty blue color in the presence of I 2 . Iodine-starch reaction is used in carrying out not only qualitative analysis, but also quantitative.
Reactions involving I 2 as a reducing agent
Iodine atoms have lower electron affinity and EO values than other halogens. On the other hand, the manifestation of some metallicity in iodine is explained by a significant decrease in the ionization energy, due to which its atoms give up electrons much more easily. In reactions with strong oxidizing agents, iodine behaves as a reducing agent, for example:
I 2 + I0HNO 3 \u003d 2HIO 3 + 10NO 2 + 4H 2 O
I 2 + 5H 2 O 2 \u003d 2HIO 3 + 4H 2 O
I 2 + 5Cl 2 + 6H 2 O \u003d 2HIO 3 + 10HCl
Hydrogen bromide and hydrogen iodide
HBr and HI are very similar in physical and chemical properties to HCl, therefore, attention should be paid only to practically important differences that must be taken into account when obtaining these substances.
Thermal instability HBr and HI
HBr and HI molecules are less stable than HCl, so their synthesis from simple substances is difficult due to the reversibility of the reaction (especially in the case of HI).
H 2 + I 2 → 2HI
Br - and I - anions are stronger reducing agents than Cl - anions.
HCI is obtained by the action of conc. H 2 SO 4 to chlorides (for example, solid NaCl). Hydrogen bromide and hydrogen iodide cannot be obtained in this way, since they are oxidized with conc. H 2 SO 4 to free halogens:
2KVg + 2H 2 SO 4 \u003d Br 2 + SO 2 + 2H 2 O + K 2 SO 4
6KI + 4H 2 SO 4 \u003d 3I 2 + S + 4H 2 O + 3K 2 SO 4
Obtaining HBr and HI:
1) from bromides and iodides
It is necessary to displace HBr and HI from their salts with non-volatile non-oxidizing phosphoric acid
KVg + H 3 PO 4 \u003d HBr + KN 2 PO 4
2) hydrolysis of non-metal halides
KI + H 3 PO 4 \u003d HI + KN 2 PO 4
3) reduction of free halogens in aqueous solutions
РВr 3 + ЗН 2 O = H 3 PO 3 + ЗНВr
PI 3 + ZN 2 O \u003d H 3 PO 3 + 3HI
Br 2 + SO 2 + 2H 2 O \u003d 2HBr + H 2 SO 4
l 2 + H 2 S = 2HI + S↓
4Br 2 + BaS + 4Н 2 O = 8HBr + BaSO 4
3) CH3 O CH3
4) CH3COO CH3
3. Specify the compound containing the carboxyl group:
1) aromatic alcohol
2) aldehyde
3) simple ether
4. Specify the compound containing the carbonyl group:
1) aromatic alcohol
2) aldehyde
3) simple ether
4) unsaturated polybasic acid
5.Give a name to the connection: O
CH3 - CH - CH - C
1) 2-methyl-3-bromobutanol-1
2) 2-bromo-3-methylbutanal
3) 2-methyl-3-bromobutanal
4) 2-bromo-3-methylpropanal
6. Reaction CH3CHO+Ag2O CH3COOH+2 Ag:
1) Polycondensation
2) Esterification
3) "silver mirror"
4) Kucherova
7. The functional group of carboxylic acids is called:
1) Carbonyl
2) Hydroxyl
3) Carboxyl
4) ester
8. Acetic acid does not react with the following metal:
9. What is the name of the aldehyde:
1) 2-Methyl-3-propylbutanal;
2) 2,3-dimethylhexanal;
3) 4,5-dimethylhexanal;
4) 2-methyl-2-propylbutanal
10. Specify the general formula of carbohydrates:
11. Indicate the carbohydrate that is the main part of wood:
1) Starch
2) Cellulose
4) Maltose
12. Specify the formula of fructose:
13. Pentose, which is part of DNA, is:
1) Glucose
2) Fructose
4) Deoxyribose
14. Milk sugar is a disaccharide:
1) Sucrose
2) Maltose
3) Lactose
4) Galactose
15. Beet or cane sugar is a disaccharide:
1) Maltose
2) Sucrose
3) Galactose
4) Lactose
16. Malt Sugar:
1) Galactose
2) Sucrose
3) Lactose
4) Maltose
17. In plant cells, starch performs the following function:
1) Transfer of hereditary information
2) Supply of nutrients
3) Construction and structural
4) Catalyst for biological processes
18. In plant cells, cellulose performs the following function:
1) Supply of nutrients
2) Catalyst of biological processes
3) Construction and structural
4) Transfer of hereditary information
19. Give a name to the connection:
CH3 - CH - CH - CH3
1) 3-methylbutanol-2 3) 3-methylpropanone-2
2) 2-methylbutanol-3 4) 2-methylpropanal-2
20. Write the equation for a chemical reaction and give it a name:
R1 - C + HO - R2 ↔
1) hydration 3) attachment
2) esterification reaction 4) substitution
Among the characteristics listed below, select those that, as a rule, relate to liquid fats - oils:
1) They are of plant origin
2) They are of animal origin
3) Highly soluble in water
4) Highly soluble in organic solvents
7) Discolor bromine water
8) Are esters of glycerol
Give your answer as a sequence of numbers in ascending order.
B-2 Match a fat feature with an example of a fat that matches that feature. Give your answer as a sequence of numbers corresponding to letters in alphabetical order:
CHARACTERISTIC:
A) solid fat of vegetable origin
B) solid fat of animal origin
C) liquid fat of animal origin
D) liquid fat of vegetable origin
1) Linseed oil
2) Butter
3) Fish oil
4) Palm oil
Hello. Help me please. 1) Specify the number of isomeric carboxylic acids of composition C5H10O2: a) 3 b) 2 c) 4 d)2) When dissolved in water, 1 mol of acetic anhydride forms:
a) 2 moles of ethanol
b) 2 mol of ethanol
c) 2 mol of acetic acid
d) 1 mol of methyl acetate
3) What substances does sodium acetate react with:
a) hydrochloric acid
b) Sodium hydroxide when heated
c) Carbonic acid
4) When interacting ethanol and carbon monoxide (II) under appropriate conditions, it turns out?
a) ethanal
b) propanal
c) propanoic acid
d) methyl acetate
5) What type of reactions can unsaturated carboxylic acids enter into: a) Oxidation
b) Polymerization
c) Connections
d) Esterification
6) What substances does formic acid react with:
a) Copper II chloride
b) Sodium sulfate
c) Potassium bicarbonate
d) ammonia solution of silver oxide I
7) Unlike stearic acid, oleic acid:
a) Liquid at room temperature
b) soluble in water
c) Discolors bromine water
d) Reacts with alkalis
8) What substances react with water:
a) linoleic acid
b) ethanol
c) propanal
d) propane
9) What single reagent can be used to distinguish between solutions of glycerol, propanal, and ethanoic acid:
a) bromine water
b) potassium carbonate
c) copper hydroxide II
d) nitric acid
10) In reactions with what substances with the participation of acetic acid, a hydrostrong group is split off from its molecule:
a) metals
b) alkalis
c) alcohols
d) metal carbonates
Help pliz, solve two problems!: (put 11 points 1) With which of the following substances: sodium hydroxide, bromine water, dimethyl ether -Bromine is a substance that, like mercury, is in a liquid state at room temperature. It is highly toxic but is widely used in the chemical industry and laboratories. Belongs to the group of halogens, but weaker than chlorine. When passing through water, it forms a solution called bromine water.
Bromine and the preparation of bromine water
The element itself is a red-brown liquid with a strong, unpleasant odor. It’s not worth breathing it, since you can get poisoned, and hardly anyone will have such a desire. The name itself speaks of this property, because bromine in translation from ancient Greek means "stink", "stinky".
The molecule is diatomic, and its formula is Br 2 . The element itself was found in 1826 and brought fame to its discoverer, the young teacher Antoine Balard. Bromine is distributed everywhere, but most of all it is in sea water and salt lakes. It is not the substance itself that is used in production and laboratories, but its solution, which is easy to prepare.
Prepare a solution of bromine water only in a fume hood due to the poisonous vapors. To do this, take bromine in a volume of one milliliter and pour it into water (distilled, otherwise you will get a lot of unnecessary impurities) with a volume of 250 milliliters, intensively stirring with a glass rod. Bromine water is ready. You need to store it only in dark glass, tightly closed. Be careful, because, in contact with the skin, bromine causes severe and painful burns. If contact occurs, immediately flush the affected area with water.
Bromine water composition
Properties chemical and physical
In appearance, bromine water is an orange-yellow liquid that has taken its unpleasant odor from the main substance. The temperature at which the solution freezes is quite low. Even at -20°C it is liquid.
Like all halogen solutions, bromine water is an excellent oxidizing agent, but weaker than a chlorine solution. It oxidizes metals and many organic compounds, including phenols. And adding more bromine to it leads to a decrease in pH.
Application
Bromine water is used in industrial laboratories. One of the qualitative reactions to unsaturated hydrocarbons is precisely the interaction of alkenes and alkynes with a solution of bromine water. As a result, the composition becomes discolored. Breaking double and triple bonds, bromine joins, forming bromine compounds.
Discoloration of bromine water also occurs when reacting with unsaturated oils. They also contain double and triple bonds. The interaction of potassium iodide with bromine water leads to the discoloration of the first and the gradual release of free iodine molecules (I 2). It is possible to carry out a qualitative reaction with bromine water for the presence of CuCl, with the addition of a small amount of ammonia solution, redness will occur.
In medicine, bromine water is used in the manufacture of drugs. There used to be a legend that bromine is added to soldiers' food to reduce potency. But there are no grounds for this statement, since substances containing bromine do not have any effect on male power. They simply act on the nervous system as a sedative and mild sleeping pill.
But when using medicinal substances containing bromine, one should be very careful, since prolonged use can cause a disease such as bromism. The main symptoms of the disease are a general breakdown, accompanied by a rash on the skin and lack of appetite. To normalize the condition, it is urgent to remove the active substance from the body. To do this, prescribe a large amount of liquid and food with a high salt content.
Bromine water is also used in construction - at different stages of the production of substances that protect fabrics, wood, and building materials from flames. These substances are also called flame retardants. Bromine water and bromides are used in flights, for the oxidation of rocket fuel, in oil production, and in agriculture (production of pesticides and insecticides).
