Absolute zero temperature is the point at which molecules stop moving. Fundamentals of the molecular-kinetic theory of the structure of matter

Fundamentals of the molecular-kinetic theory of the structure of matter

The fundamentals of the molecular kinetic theory were developed by M.V. Lomonosov, L. Boltzmann, J. Maxwell and others. This theory is based on the following provisions:

1. All substances consist of the smallest particles - molecules. Molecules in complex substances consist of even smaller particles - atoms. Different combinations of atoms create kinds of molecules. An atom consists of a positively charged nucleus surrounded by a negatively charged electron shell. The mass of molecules and atoms is measured in atomic mass units (amu). The diameter of atoms and molecules is of the order of 10 - 10 cm. The amount of a substance that contains the number of particles (atoms or molecules) equal to the number of atoms in 0.012 kg of carbon isotope C is called we pray.

The number of particles containing a mole (kilomole) of a substance is called Avogadro's number. N \u003d 6.023 * 10 kmol. Names the mass of the moth molar mass. Between atoms and molecules there are forces of mutual attraction and repulsion. As the distance (r) between molecules increases, the repulsive forces decrease faster than the attractive forces. At a certain distance (r), the repulsive and attractive forces are equal, and the molecules are in a state of stable equilibrium. The interaction forces are inversely proportional to the nth power of the distance between molecules (for f, n = 7; for f, n takes a value from 9 to 15). The distance r between molecules corresponds to the minimum of their potential energy. To change a distance other than r, it is required to expend work either against repulsive forces or against attractive forces; then. the position of stable equilibrium of molecules corresponds to the minimum of their potential energy. The molecules that make up the body are in a state of continuous random movement.

Molecules collide with each other, changing speed both in magnitude and in direction. In this case, their total kinetic energy is redistributed. A body consisting of molecules is considered as a system of moving and interacting particles. Such a system of molecules has an energy consisting of the potential energy of particle interaction and the kinetic energy of particle motion. This energy is called body's internal energy. The amount of internal energy transferred between bodies during heat exchange is called the amount of heat (joule, cal). Joule - SI. 1 cal = 4.18 J. Atoms and molecules are in continuous motion, which is called thermal. The main property of thermal motion is its continuity (chaoticity). To quantitatively characterize the intensity of thermal motion, the concept of body temperature is introduced. The more intense the thermal movement of molecules in the body, the higher its temperature. When two bodies come into contact, energy passes from a more heated body to a less heated one, and in the end is established state of thermal equilibrium.

From the point of view of molecular kinetic concepts temperature is a quantity that characterizes the average kinetic energy of the translational motion of molecules or atoms. The unit of measure for heat temperature is degree.(One hundredth of the difference between the boiling and freezing points of pure water at atmospheric pressure). The Kelvin absolute temperature scale was introduced into physics. A degree Celsius is equal to a degree Kelvin. At a temperature of -273 C, the translational motion of gas molecules (absolute zero) should stop, i.e. the system (body) has the lowest possible energy.

The main provisions of the molecular-kinetic theory of the structure of matter are confirmed by numerous experiments and phenomena (diffusion, Brownian motion, mixing of liquids, compressibility of various substances, dissolution of solids in liquids, etc.). Modern experimental methods - X-ray diffraction analysis, observations with an electron microscope, and others - have enriched our understanding of the structure of matter. In a gas, there are relatively large distances between molecules, and the forces of attraction are negligible. Gas molecules tend to always be evenly distributed over the entire volume it occupies. The gas exerts pressure on the walls of the vessel in which it is located. This pressure is due to the impacts of moving molecules. When studying the kinetic theory of gas, one considers the so-called ideal gas. A gas in which we neglect the forces of intermolecular interaction and the volume of gas molecules. Assuming that during collisions the molecules of an ideal gas are like absolutely elastic balls.

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The thermal motion of the molecules of substances in the liquid state is similar to their motion for substances in the crystalline and gaseous states. In crystals, the thermal motion of molecules is expressed mainly in vibrations of molecules about equilibrium positions, which practically do not change with time. The thermal motion of molecules in gases is mainly their translational movement and rotation, the directions of which change in collisions.

The thermal movement of molecules of a substance on the surface of a substrate is called migration. During migration, the possibility of collision of molecules appears - two and less often three among themselves. The colliding molecules are combined under the action of van der Waals forces. So, doublets and triplets are formed. They are more difficult to desorb than single molecules, since their bonds with the surface are noticeably stronger. These formations are active centers during the condensation of subsequent settling molecules.

Since the thermal motion of the molecules of the substance of the body violates their orderly arrangement, the magnetization decreases with increasing temperature.

Since the thermal motion of the molecules of the substance of the body violates their orderly arrangement, the magnetization decreases with increasing temperature. If this body is removed from the external field, then the chaotic movement of molecules will lead to its complete demagnetization.

Saturated vapor pressure is created by the thermal motion of the molecules of a substance in the vapor phase at a certain temperature.

The gaseous state occurs when the energy of the thermal motion of the molecules of a substance exceeds the energy of their interaction. The molecules of a substance in this state acquire a rectilinear translational motion, and the individual properties of substances are lost, and they obey the laws common to all gases. Gaseous bodies do not have their own shape and easily change their volume when exposed to external forces or when the temperature changes.

Absolute zero (0 K) is characterized by the cessation of the thermal motion of the molecules of a substance and corresponds to a temperature lying below 0 C by 273 16 C.

The kinetic theory of matter makes it possible to establish a connection between pressure and the kinetic energy of the thermal motion of the molecules of matter.

If the internal motions in molecules are associated with their external thermal motion, then it is impossible to understand the properties of a substance, its chemical behavior, without studying this connection, without taking into account those factors that affect the thermal motion of the molecules of a substance (temperature, pressure, medium, etc.). ) and through this thermal motion also influence the state of internal motion in each individual molecule.

Thus, it was found that any substance can be transferred from a gaseous state to a liquid. However, each substance can experience such a transformation only at temperatures below a certain, so-called critical temperature Tk. Above the critical temperature, the substance does not turn into a liquid or a solid at any pressure. Obviously, at a critical temperature, the average kinetic energy of the thermal motion of the molecules of a substance exceeds the potential energy of their binding in a liquid or solid. Since the attractive forces acting between the molecules of different substances are different, the potential energy of their binding is also not the same, hence the values ​​of the critical temperature for different substances also turn out to be different.

The relaxation times 1 and T2 are introduced above as constants, which must be determined from experience. The values ​​of 7 measured for various substances lie in a wide range from K) 4 sec for solutions of paramagnetic salts to several. Experimental data indicate a close connection between the values ​​of relaxation times and the structure and nature of the thermal motion of the molecules of a substance.

The absolute temperature T, K, characterizes the degree of heating of the body. In particular, as the initial values ​​that serve in the construction of the International Practical Celsius Temperature Scale to establish the origin of the temperature and its unit of measurement - degrees, the melting temperature of ice (0 C) and boiling point of water (100 C) at normal atmospheric pressure are taken. Temperatures above 0 C are considered positive, and temperatures below 0 C are considered negative. In the SI system of units, temperature calculations are made from absolute zero in degrees of the thermodynamic Kelvin scale. The absolute zero of this scale (0 K) is characterized by the cessation of the thermal motion of the molecules of a substance and corresponds to a temperature of -273 15 C on the Celsius scale. Thus, both scales differ only in the starting point of reference, and the division price (degree) is the same for them.

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1. In 1827, the English botanist R. Brown, studying pollen particles suspended in water with a microscope, noticed that these particles move randomly; they seem to tremble in the water.

The reason for the movement of pollen particles could not be explained for a long time. Brown himself suggested in the beginning that they move because they are alive. They tried to explain the movement of particles by unequal heating of different parts of the vessel, chemical reactions taking place, etc. Only much later did they understand the true cause of the movement of particles suspended in water. This reason is the movement of molecules.

The water molecules in which the pollen particle is located move and hit it. In this case, an unequal number of molecules hits the particle from different sides, which leads to its movement.

Let at the moment of time ​ \ (t_1 \) ​ under the influence of impacts of water molecules, the particle moved from point A to point B. At the next point in time, a larger number of molecules hit the particle from the other side, and the direction of its movement changes, it moves from t. In t. C. Thus, the movement of a particle of pollen is a consequence of the movement and impacts of water molecules on it, in which the pollen is located (Fig. 65). A similar phenomenon can be observed if particles of paint or soot are placed in water.

Figure 65 shows the trajectory of a pollen particle. It can be seen that it is impossible to speak of any particular direction of its movement; it changes all the time.

Since the motion of a particle is a consequence of the motion of molecules, we can conclude that molecules move randomly (chaotically). In other words, it is impossible to single out any particular direction in which all molecules move.

The movement of molecules never stops. It can be said that it continuously. The continuous random movement of atoms and molecules is called thermal motion. This name is determined by the fact that the speed of movement of molecules depends on the temperature of the body.

Since bodies consist of a large number of molecules and the movement of molecules is random, it is impossible to say exactly how many impacts this or that molecule will experience from others. Therefore, they say that the position of the molecule, its speed at each moment of time random. However, this does not mean that the movement of molecules does not obey certain laws. In particular, although the velocities of the molecules at some point in time are different, most of them have velocities close to some definite value. Usually, when speaking about the speed of movement of molecules, they mean average speed​\((v_(cp)) \) .

2. From the point of view of the movement of molecules, one can explain such a phenomenon as diffusion.

Diffusion is the phenomenon of the penetration of molecules of one substance into the gaps between the molecules of another substance.

We smell perfume at some distance from the bottle. This is due to the fact that the molecules of spirits, like the molecules of air, move. There are gaps between molecules. Perfume molecules penetrate into the gaps between air molecules, and air molecules into the gaps between perfume molecules.

Diffusion of liquids can be observed if a solution of copper sulfate is poured into a beaker, and water is poured on top so that there is a sharp boundary between these liquids. After two or three days, you will notice that the border will no longer be so sharp; in a week it will be completely washed out. After a month, the liquid will become homogeneous and will be colored the same throughout the vessel (Fig. 66).

In this experiment, copper sulfate molecules penetrate into the spaces between water molecules, and water molecules into the spaces between copper sulfate molecules. It should be borne in mind that the density of copper sulfate is greater than the density of water.

Experiments show that diffusion in gases occurs faster than in liquids. This is due to the fact that gases have a lower density than liquids, i.e. gas molecules are located at large distances from each other. Diffusion occurs even more slowly in solids, since the molecules of solids are even closer to each other than the molecules of liquids.

In nature, technology, everyday life, you can find many phenomena in which diffusion is manifested: staining, gluing, etc. Diffusion is of great importance in human life. In particular, due to diffusion, oxygen enters the human body not only through the lungs, but also through the skin. For the same reason, nutrients pass from the intestines into the blood.

The diffusion rate depends not only on the state of aggregation of the substance, but also on temperature.

If you prepare two vessels with water and blue vitriol for a diffusion experiment, and put one of them in the refrigerator and leave the other in the room, you will find that at a higher temperature, diffusion will occur faster. This is because as the temperature rises, the molecules move faster. Thus, the speed of the molecules
and body temperature are related.

The greater the average speed of movement of the body's molecules, the higher its temperature.

3. Molecular physics, unlike mechanics, studies systems (bodies) consisting of a large number of particles. These bodies may be in different states.

The quantities characterizing the state of the system (body) are called state parameters. The parameters of the state include pressure, volume, temperature.

Such a state of the system is possible, in which the parameters characterizing it remain unchanged for an arbitrarily long time in the absence of external influences. This state is called thermal equilibrium.

So, the volume, temperature, pressure of a liquid in a vessel that is in thermal equilibrium with the air in the room do not change if there are no external reasons for this.

4. The state of thermal equilibrium of the system characterizes such a parameter as temperature. Its peculiarity is that the temperature value in all parts of the system, which is in a state of thermal equilibrium, is the same. If you lower a silver spoon (or a spoon made of any other metal) into a glass of hot water, the spoon will heat up and the water will cool. This will happen until thermal equilibrium is reached, at which the spoon and water will have the same temperature. In any case, if we take two differently heated bodies and bring them into contact, then the hotter body will cool down, and the colder one will heat up. After some time, the system consisting of these two bodies will come into thermal equilibrium, and the temperature of these bodies will become the same.

So, the temperature of the spoon and water will become the same when they come into thermal equilibrium.

Temperature is a physical quantity that characterizes the thermal state of a body.

So, the temperature of hot water is higher than cold; In winter, the air temperature outside is lower than in summer.

The temperature unit is degree Celsius (°C). Temperature is measured thermometer.

The device of a thermometer and, accordingly, the method of measuring temperature is based on the dependence of the properties of bodies on temperature, in particular, the property of a body to expand when heated. Different bodies can be used in thermometers: both liquid (alcohol, mercury), and solid (metals) and gaseous. They are called thermometric bodies. A thermometric body (liquid or gas) is placed in a tube equipped with a scale, it is brought into contact with the body whose temperature is to be measured.

When constructing the scale, two main (reference, reference) points are selected, to which certain temperature values ​​are assigned, and the interval between them is divided into several parts. The value of each part corresponds to the temperature unit on this scale.

5. There are different temperature scales. One of the most common scales in practice is the Celsius scale. The main points of this scale are the melting temperature of ice and the boiling point of water at normal atmospheric pressure (760 mm Hg). The first point was assigned a value of 0 °C, and the second - 100 °C. The distance between these points was divided into 100 equal parts and received the Celsius scale. The temperature unit on this scale is 1°C. In addition to the Celsius scale, the temperature scale is widely used, called absolute(thermodynamic) temperature scale, or Kelvin scale. For zero on this scale, a temperature of -273 ° C (more precisely -273.15 ° C) is taken. This temperature is called absolute zero temperatures and is denoted by 0 K. The unit of temperature is one kelvin (1 K); it is equal to 1 degree Celsius. Accordingly, the melting temperature of ice on the absolute temperature scale is 273 K (273.15 K), and the boiling point of water is 373 K (373.15 K).

Temperature on an absolute scale is denoted by the letter ​ \ (T \) . The relationship between absolute temperature ​\((T) \) ​ and Celsius temperature ​\(((t)^\circ) \) ​ is expressed by the formula:

\[ T=t^\circ+273 \]

Part 1

1. Brownian motion of paint particles in water is a consequence of

1) attraction between atoms and molecules
2) repulsion between atoms and molecules
3) chaotic and continuous motion of molecules
4) displacement of water layers due to the temperature difference between the lower and upper layers

2. In which of the following situations are we talking about Brownian motion?

1) random movement of dust particles in the air
2) the spread of odors
3) oscillatory motion of particles in the nodes of the crystal lattice
4) translational movement of gas molecules

3. What do the words mean: "Molecules move randomly"?

A. There is no preferred direction of movement of molecules.
B. The movement of molecules does not obey any laws.

Correct answer

1) only A
2) only B
3) both A and B
4) neither A nor B

4. The position of the molecular-kinetic theory of the structure of matter that particles of matter participate in continuous chaotic motion refers to

1) only for gases
2) only liquids
3) only for gases and liquids
4) to gases, liquids and solids

5. What (s) position (s) of the molecular-kinetic theory of the structure of matter confirms the phenomenon of diffusion?

A. Molecules are in continuous chaotic motion
B. There are gaps between molecules

Correct answer

1) only A
2) only B
3) both A and B
4) neither A nor B

6. At the same temperature, diffusion in liquids occurs

1) faster than in solids
2) faster than in gases
3) slower than in solids
4) at the same speed as in gases

7. Indicate a pair of substances, the diffusion rate of which is the smallest, all other things being equal

1) a solution of copper sulfate and water
2) ether vapor and air
3) iron and aluminum plates
4) water and alcohol

8. Water boils and turns into steam at 100°C. The average speed of movement of vapor molecules

1) is equal to the average speed of movement of water molecules
2) more than the average speed of movement of water molecules
3) less than the average speed of movement of water molecules
4) depends on atmospheric pressure

9. Thermal motion of molecules

1) stops at 0 °C
2) stops at 100 °C
3) continuously
4) has a certain direction

10. Water is heated from room temperature to 80°C. What happens to the average speed of water molecules?

1) decreases
2) increases
3) does not change
4) first increases, and starting from a certain temperature value, remains unchanged

11. One glass of water is on the table in a warm room, the other is in the refrigerator. The average speed of movement of water molecules in a glass standing in a refrigerator

1) is equal to the average speed of movement of water molecules in a glass standing on a table
2) more than the average speed of movement of water molecules in a glass standing on a table
3) less than the average speed of movement of water molecules in a glass standing on a table
4) equal to zero

12. From the list of statements below, choose the two correct ones and write their numbers in the table

1) thermal motion of molecules occurs only at a temperature greater than 0 ° C
2) diffusion in solids is impossible
3) attractive and repulsive forces act simultaneously between molecules
4) a molecule is the smallest particle of a substance
5) the diffusion rate increases with increasing temperature

13. A cotton swab soaked in perfume was brought to the physics office, and a vessel into which a solution of copper sulphate (a blue solution) was poured, and water was carefully poured on top (Fig. 1). It was noticed that the smell of perfume spread throughout the volume of the entire cabinet in a few minutes, while the boundary between the two liquids in the vessel disappeared only after two weeks (Fig. 2).

Choose from the proposed list two statements that correspond to the results of the experimental observations. List their numbers.

1) The diffusion process can be observed in gases and liquids.
2) The diffusion rate depends on the temperature of the substance.
3) The diffusion rate depends on the aggregate state of the substance.
4) The diffusion rate depends on the type of liquids.
5) In solids, the diffusion rate is the lowest.

Answers


















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Goals.

  • Educational.
    • Give the concept of temperature as a measure of average kinetic energy; consider the history of the creation of thermometers, compare various temperature scales; to form the ability to apply the acquired knowledge to solve problems and perform practical tasks, to expand the horizons of students in the field of thermal phenomena.
  • Educational.
    • Developing the ability to listen to the interlocutor, to express their own point of view
  • Developing.
    • The development of students' voluntary attention, thinking (the ability to analyze, compare, build analogies, draw conclusions.), Cognitive interest (based on a physical experiment);
    • formation of worldview concepts about the cognizability of the world.

DURING THE CLASSES

Hello, have a seat.

When studying mechanics, we were interested in the motion of bodies. Now we will consider the phenomena associated with a change in the properties of bodies at rest. We will study the heating and cooling of air, the melting of ice, the melting of metals, the boiling of water, etc. Such phenomena are called thermal phenomena.

We know that when cold water is heated, it first becomes warm and then hot. The metal part taken out of the flame gradually cools. The air surrounding the hot water heaters becomes hot, etc.

The words "cold", "warm", "hot" denote the thermal state of bodies. The quantity characterizing the thermal state of bodies is temperature.

Everyone knows that the temperature of hot water is higher than the temperature of cold water. In winter, the air temperature outside is lower than in summer.

All molecules of any substance are continuously and randomly (chaotically) moving.

The random random motion of molecules is called thermal motion.

What is the difference between thermal motion and mechanical motion?

It involves many particles with different trajectories. The movement never stops. (Example: Brownian motion)

Demonstration of the Brownian motion model

What does thermal motion depend on?

  • Experiment number 1: Let's put a piece of sugar in cold water, and the other in hot. Which will dissolve faster?
  • Experiment number 2: Let's put 2 pieces of sugar (one larger than the other) in cold water. Which will dissolve faster?

The question of what temperature is, turned out to be very difficult. What is the difference between hot water and cold water? For a long time there was no clear answer to this question. Today we know that at any temperature, water is made up of the same molecules. Then what exactly changes in water as its temperature increases? We have seen from experience that sugar dissolves much faster in hot water. Dissolution occurs due to diffusion. In this way, diffusion at higher temperatures is faster than at lower temperatures.

But the cause of diffusion is the movement of molecules. This means that there is a relationship between the speed of movement of molecules and the temperature of a body: In a body with a higher temperature, the molecules move faster.

But the temperature depends not only on the average speed of the molecules. For example, oxygen, whose average molecular velocity is 440 m/s, has a temperature of 20 °C, while nitrogen, with the same average molecular velocity, has a temperature of 16 °C. The lower temperature of nitrogen is due to the fact that nitrogen molecules are lighter than oxygen molecules. Thus, the temperature of a substance is determined not only by the average velocity of its molecules, but also by their mass. We see the same in experiment No. 2.

We know quantities that depend on both the speed and the mass of the particle. These are momentum and kinetic energy. Scientists have established that it is the kinetic energy of the molecules that determines the temperature of the body: temperature is a measure of the average kinetic energy of the particles of a body; the greater this energy, the higher the temperature of the body.

So, when bodies are heated, the average kinetic energy of molecules increases, and they begin to move faster; when cooled, the energy of the molecules decreases, and they begin to move more slowly.

Temperature is a value that characterizes the thermal state of the body. A measure of the "warmth" of a body. The higher the temperature of a body, the more energy its atoms and molecules have on average.

Can one only rely on one's own sensations to judge the degree of body heat?

  • Experience number 1: Touch a wooden object with one hand and a metal object with the other.

Compare sensations

Although both objects are at the same temperature, one hand will feel cold and the other warm

  • Experience number 2: take three vessels with hot, warm and cold water. Dip one hand into a vessel of cold water and the other into a vessel of hot water. After a while, both hands are lowered into a vessel with warm water.

Compare sensations

The hand that was in hot water now feels cold, and the hand that was in cold water now feels warm, even though both hands are in the same vessel

We have proven that our feelings are subjective. Instruments are needed to confirm them.

Instruments used to measure temperature are called thermometers. The operation of such a thermometer is based on the thermal expansion of a substance. When heated, the column of the substance used in the thermometer (for example, mercury or alcohol) increases, and when cooled, it decreases. The first liquid thermometer was invented in 1631 by the French physicist J. Rey.

The temperature of the body will change until it comes into thermal equilibrium with the environment.

The law of thermal equilibrium: for any group of isolated bodies, after some time, the temperatures become the same, i.e. a state of thermal equilibrium occurs.

It should be remembered that any thermometer always shows its own temperature. To determine the temperature of the environment, the thermometer should be placed in this environment and wait until the temperature of the device stops changing, taking a value equal to the ambient temperature. When the temperature of the medium changes, the temperature of the thermometer will also change.

A medical thermometer, designed to measure the temperature of a person's body, operates somewhat differently. It belongs to the so-called maximum thermometers, fixing the highest temperature to which they were heated. Having measured your own temperature, you may notice that, being in a colder (compared to the human body) environment, the medical thermometer continues to show the same value. To return the mercury column to its original state, this thermometer must be shaken.

With a laboratory thermometer used to measure the temperature of the medium, this is not necessary.

Thermometers used in everyday life allow you to express the temperature of a substance in degrees Celsius (°C).

A. Celsius (1701-1744) - Swedish scientist who proposed the use of a centigrade temperature scale. In the Celsius temperature scale, zero (from the middle of the 18th century) is the temperature of melting ice, and 100 degrees is the boiling point of water at normal atmospheric pressure.

We will listen to the message about the history of the development of thermometers (Presentation by Sidorova E.)

Liquid thermometers are based on the principle of changing the volume of liquid that is poured into the thermometer (usually alcohol or mercury) as the ambient temperature changes. Disadvantage: different liquids expand differently, so the readings of thermometers differ: Mercury -50 0 С; glycerin -47.6 0 С

We tried to make a liquid thermometer at home. Let's see what came of it. (Video by Brykina V. Appendix 1)

We learned that there are different temperature scales. In addition to the Celsius scale, the Kelvin scale is widely used. The concept of absolute temperature was introduced by W. Thomson (Kelvin). The absolute temperature scale is called the Kelvin scale or the thermodynamic temperature scale.

The unit of absolute temperature is the kelvin (K).

Absolute zero - the lowest possible temperature at which nothing can be colder and it is theoretically impossible to extract thermal energy from a substance, the temperature at which the thermal movement of molecules stops

Absolute zero is defined as 0 K, which is approximately 273.15 °C

One Kelvin is equal to one degree T=t+273

Questions from the exam

Which of the following options for measuring the temperature of hot water with a thermometer gives a more correct result?

1) The thermometer is lowered into the water and, after taking it out of the water after a few minutes, the readings are taken.

2) The thermometer is lowered into the water and wait until the temperature stops changing. After that, without removing the thermometer from the water, take its readings.

3) The thermometer is lowered into the water and, without removing it from the water, immediately take readings

4) The thermometer is lowered into the water, then quickly removed from the water and the readings are taken

The figure shows part of the scale of a thermometer hanging outside the window. The air temperature outside is

  • 18 0 C
  • 14 0 C
  • 21 0 С
  • 22 0 С

Solve problems No. 915, 916 (“Collection of problems in physics 7-9” by V.I. Lukashik, E.V. Ivanova)

  1. Homework: Paragraph 28
  2. No. 128 D “Collection of problems in physics 7-9” V.I. Lukashik, E.V. Ivanova

Methodological support

  1. “Physics 8” S.V. Gromov, N.A. Motherland
  2. “Collection of problems in physics 7-9” V.I.Lukashik, E.V. Ivanova
  3. Drawings that are in the public domain of the Internet

The term "temperature" appeared at a time when physicists thought that warm bodies consist of a larger amount of a specific substance - caloric - than the same bodies, but cold ones. And the temperature was interpreted as a value corresponding to the amount of caloric in the body. Since then, the temperature of any body is measured in degrees. But in reality it is a measure of the kinetic energy of moving molecules, and, based on this, it should be measured in Joules, in accordance with the SI system of units.

The concept of "absolute zero temperature" comes from the second law of thermodynamics. According to it, the process of transferring heat from a cold body to a hot one is impossible. This concept was introduced by the English physicist W. Thomson. For achievements in physics, he was granted the noble title of "Lord" and the title of "Baron Kelvin". In 1848, W. Thomson (Kelvin) suggested using a temperature scale, in which he took the absolute zero temperature corresponding to the limiting cold as the starting point, and took degrees Celsius as the division price. The unit of Kelvin is 1/27316 of the temperature of the triple point of water (about 0 degrees C), i.e. the temperature at which pure water exists in three forms at once: ice, liquid water, and steam. temperature is the lowest possible low temperature at which the movement of molecules stops, and it is no longer possible to extract thermal energy from the substance. Since then, the absolute temperature scale has been named after him.

Temperature is measured on different scales

The most commonly used temperature scale is called the Celsius scale. It is built on two points: on the temperature of the phase transition of water from liquid to vapor and water to ice. A. Celsius in 1742 proposed to divide the distance between reference points into 100 intervals, and take water as zero, while the freezing point is 100 degrees. But the Swede K. Linnaeus suggested doing the opposite. Since then, water freezes at zero degrees A. Celsius. Although it should boil exactly in Celsius. Absolute zero in Celsius corresponds to minus 273.16 degrees Celsius.

There are several more temperature scales: Fahrenheit, Réaumur, Rankine, Newton, Roemer. They have different and price divisions. For example, the Réaumur scale is also built on the benchmarks of boiling and freezing of water, but it has 80 divisions. The Fahrenheit scale, which appeared in 1724, is used in everyday life only in some countries of the world, including the USA; one is the temperature of the mixture of water ice - ammonia and the other is the temperature of the human body. The scale is divided into one hundred divisions. Zero Celsius corresponds to 32 The conversion of degrees to Fahrenheit can be done using the formula: F \u003d 1.8 C + 32. Reverse translation: C \u003d (F - 32) / 1.8, where: F - degrees Fahrenheit, C - degrees Celsius. If you are too lazy to count, go to the online Celsius to Fahrenheit conversion service. In the box, type the number of degrees Celsius, click "Calculate", select "Fahrenheit" and click "Start". The result will appear immediately.

Named after the English (more precisely Scottish) physicist William J. Rankin, a former contemporary of Kelvin and one of the founders of technical thermodynamics. There are three important points in his scale: the beginning is absolute zero, the freezing point of water is 491.67 degrees Rankine and the boiling point of water is 671.67 degrees. The number of divisions between the freezing of water and its boiling in both Rankine and Fahrenheit is 180.

Most of these scales are used exclusively by physicists. And 40% of American high school students surveyed these days said they don't know what absolute zero temperature is.